Tuesday 10 October 2017

BITUMEN,ASPHALT CEMENT OR ASPHALT

Bitumen is a mixture of organic liquids that are highly viscous, black, sticky, entirely soluble in carbon disulfide, and composed primarily of highly condensed polycyclic aromatic hydrocarbons.
Naturally occurring or crude bitumen is a sticky, tar-like form of petroleum that is so thick and heavy that it must be heated or diluted before it will flow. At room temperature, it has a consistency much like cold molasses.

Detailed description
Bitumen is a mixture of organic liquids that are highly viscous, black, sticky, entirely soluble in carbon disulfide, and composed primarily of highly condensed polycyclic aromatic hydrocarbons.
Naturally occurring or crude bitumen is a sticky, tar-like form of petroleum that is so thick and heavy that it must be heated or diluted before it will flow. At room temperature, it has a consistency much like cold molassesRefined bitumen is the residual (bottom) fraction obtained by fractional distillation of crude oil. It is the heaviest fraction and the one with the highest boiling point, boiling at 525 °C (977 °F).

History
The use of bitumen for waterproofing and as an adhesive dates at least to the fourth millennium B.C., when the Sumerians used it in statuary, mortaring brick walls, waterproofing baths and drains, in stair treads, and for shipbuilding. Other cultures such as Babylon, India, Persia, Egypt, and ancient Greece and Rome continued these uses, and in several cases the bitumen has continued to hold components securely together to this day. In the Book of Genesis, bitumen was used to waterproof Noah's Ark and to bind the bricks of the Tower of Babel. Although its existence has not been confirmed, a one-kilometer tunnel beneath the river Euphrates at Babylon in the time of Queen Semiramis (ca. 700 B.C.) was reportedly constructed of burnt bricks covered with bitumen as a waterproofing agent.
Modern usage
Bitumen is still the preferred geological term for naturally occurring deposits of the solid or semi-solid form of petroleum. Bituminous rock is a form of sandstone impregnated with bitumen. Bitumen is sometimes incorrectly called "tar". Technically, tar is a black viscous material obtained from the destructive distillation of coal and is chemically distinct from bitumen. In Australian English, bitumen is sometimes used as the generic term for road surfaces. In Canadian English, the word bitumen is used to refer to the vast Canadian deposits of extremely heavy crude oil, while asphalt is used for the oil refinery product used to pave roads and manufacture roof shingles. Diluted bitumen (diluted with naphtha to make it flow in pipelines) is known as dilbit in the Canadian petroleum industry, while bitumen "upgraded" to synthetic crude oil is known as syncrude and syncrude blended with bitumen as "synbit".
Uses
Bitumen is primarily used in the production of asphalt, which is mixed with mineral aggregates to form paving materials. Its other uses are for bituminous waterproofing products, including the use of bitumen in the production of roofing felt and for sealing flat roofs.
Most natural bitumens contain sulfur and several heavy metals such as nickelvanadiumleadchromiummercury and also arsenicselenium, and other toxic elements. Bitumens can provide good preservation of plants and animal fossils.
Naturally occurring crude bitumen impregnated in sedimentary rock is the prime feed stock for petroleum production from "oil sands", currently under development in Alberta, Canada. Canada has most of the world's supply of natural bitumen, covering 140,000 square kilometres (an area larger than England), giving it the second largest proven oil reserves in the world. The Athabasca oil sands is the largest bitumen deposit in Canada and the only one accessible to surface mining, although recent technological breakthroughs have resulted in deeper deposits becoming producible by in-situ methods. Because of oil price increases since 2003, upgrading bitumen to synthetic crude oil has become highly profitable. As of 2006 Canadian crude bitumen production averaged about 1.1 million barrels (170,000 m3) per day and was projected to rise to 4.4 million barrels (700,000 m3) per day by 2020. The total amount of crude bitumen in Alberta which could be extracted is estimated to be about 310 billion barrels (50×109 m3), which at a rate of 4.4 million barrels per day would last about 200 years.
In the past, bitumen was used to waterproof boats, and even as a coating for buildings with some additives. The Greek historian Herodotus said hot bitumen was used as mortar in the walls of Babylon. It is also possible that the city of Carthage was easily burnt due to extensive use of bitumen in construction.
Vessels for the heating of bitumen or bituminous compounds are usually subject to specific conditions in public liability insurance policies, similar to those required for blow torches, welders, and flame-cutting equipment.
Bitumen was also used in early photographic technology.The bitumen used in his experiments were smeared on pewter plates and then exposed to light, thus making a black and white image. It was similarly used to print millions of photochrom postcards.
Thin bitumen plates are sometimes used by computer enthusiasts for silencing computer cases or noisy computer parts such as the hard drive. Bitumen layers are baked onto the outside of high end dishwashers to provide sound insulation.

Bitumen also is used in paint and marker inks by some graffiti supply companies (primarily Molotow) to increase the weather resistance and permanence of the paint and/or ink, and to make the color much darker.

PRICE
$265/MT

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ZIRCONIA OR BADDELEYITE MINERAL[ZrO2]

Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. 
Detailed description

Baddeleyite is a refractory mineral, with a melting point of 2700 °C. Hafnium is a substituting impurity and may be present in quantities ranging from 0.1 to several percent.
It can be found in igneous rocks containing potassium feldspar and plagioclase. Baddeleyite is commonly found with zircon (ZrSiO4), yet it forms in places with lower silica content, such as mafic rocks. This is because baddeleyite tends to become zircon where there is higher silica content, hence why both minerals can be found together. It belongs to the monoclinic-prismatic class, of the P21/c crystal system. It has been used for geochronology.

Geologic occurrence

Baddeleyite was first found in Sri Lanka in 1892. It can be found in numerous terrestrial and lunar rocks. Some of these terrestrial rocks are carbonatite, kimberlite, alkaline syenite, some rocks of layered mafic intrusions, diabase dikes, gabbroid sills and anorthosite.[4] Some examples of lunar rocks are tektites, meteorites and lunar basalt. Studies have shown that zircon and baddeleyite can be recovered from some anorthositic rocks in Proterozoic anorthosite complexes.[5] Places where these Proterozoic anorthosite complexes can be found are: the Laramie Anorthosite Complex in Wyoming, the Nain and Grenville provinces of Canada, the Vico Volcanic Complex in Italy,[6] and Minas Gerais and Jacupiranga, São Paulo, Brazil. Baddeleyite forms in igneous rocks low in silica, it can be found in rocks containing potassium feldspar and plagioclase. It has been observed in thin section that baddeleyite forms within plagioclase grains. Associated minerals include ilmenite, zirkelite, apatite, magnetite, perovskite, fluorite, nepheline, pyrochlore and allanite.[1]
Because of their refractory nature and stability under diverse conditions, baddeleyite grains, along with zircon, are used for uranium-lead radiometric age determinations.

Structure

There has been some dispute in the structure of baddeleyite. Originally, the mineral was assigned to the 8-fold coordination by Naray Szabo. This structure was ruled out due to the inaccuracy of the data used to establish it.
Baddeleyite has the group symmetry P21/c with four ZrO2 in the unit cell. It has unit cell dimensions of: a = 5.169 b = 5.232 c = 5.341 Å (all ± 0.008 Å), β = 99˚15ˊ ± 10ˊ.
The coordination number for ZrO2 has been found to be 7. The mineral has two types of separations. The first being the seven shortest Zr-O, ranging from 2.04 to 2.26 Å, and the second Zr-O separation is 3.77 Å. Because of this, the coordination of baddeleyite was determined to be sevenfold. Baddeleyite's structure is a combination of tetrahedrally coordinated oxide ions parallel to (100) with triangular coordinated oxide ions. This explains baddeleyite's tendency to twin along the (100) planes. It has been observed that baddeleyite without twinning is extremely rare.[8]

Composition

Baddeleyite belongs to the oxide group, having a composition of ZrO2. Similar minerals belonging to the same group are the rutile group: rutile (TiO2), pyrolusite (MnO2), cassiterite (SnO2), uraninite (UO2) and thorianite (ThO2). Baddeleyite is chemically homogeneous, but it may contain impurities such as Ti, Hf, and Fe.[9] Higher concentrations of Ti and Fe are restricted to mafic-ultramafic rocks.

Physical properties


Baddeleyite is black in color with a submetallic lustre. It has a 6.5 hardness, and a brownish-white streak. Baddeleyite can also be brown, brownish black, green, and greenish brown. Its streak is white, or brownish white. It has a distinct cleavage along {001} and tends to twin along (100). It belongs to the monoclinic system and is part of the P21/c group.

PRICE
$4.62/KG OR $2.1/IB

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ALUM-K,TAWAS, OR POTASSIUM ALUMINIUM SULPHATE[MINERAL]

Potassium alum, potash alum, tawas, or potassium aluminum sulfate is a chemical compound: the potassium double sulfate ofaluminium. Its chemical formula is KAl(SO4)2 and it is commonly found in its dodecahydrate form as KAl(SO4)2.12(H2O).

Detailed description:

Alum is the common name for this chemical compound,given the nomenclature of potassium aluminum sulfate dodecahydrate. It is commonly used in water purificationleather tanning, dyeing, fireproof textiles,and baking powder. It also has cosmetic uses as a deodorant, as an aftershave treatment and as a styptic for minor bleeding from shaving.

PRICE
$25/KG

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Monday 9 October 2017

BORAX(MINERAL)

Listing description

Borax occurs in arid regions, forming from evaporation of saline lakes. Borax is also synthetically formed as a by-product of mining operations of borate deposits, and most of the specimens from the famous mine at Boron, California, are formed this way.

The first Borax specimens came several 
dry lake deposits in Tibet. They were shipped in large quantities by ancient caravans for profit. Much greater deposits were later found in the southwestern U.S., from which most of the world's industrial borax comes.
Detailed description
 Borax specimens are translucent when fresh, but eventually lose water in their chemicalstructure and turn opaque, developing a white powder on their surfaces. If allowed to dehydrate, they will eventually crumble into a white powder. Because of this property, known asefflorescence, Borax is not commonly seen in collections. When a Borax specimen loses water, it alters into a new mineral called Tincalconite, which contains the same elements as Borax but has half the water, and crystallizes in a different crystal system.

PRICE


$2758.79/KG OR $1253.99

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BORON ORE

Listing description
Boron ( /ˈbɔərɒn/) is the chemical element with atomic number 5 and the chemical symbol B. Boron is a metalloid. A low-abundance element in both the solar system and the Earth's crust, boron is concentrated on Earth by the water-solubility of its more common naturally-occurring compounds, the borate minerals. These are mined industrially as evaporate ores, such as borax and kernite.
Detailed description
Elemental boron is not found naturally. Industrially, very pure isolated boron is produced with difficulty, as boron tends to form refractory materials containing small amounts of carbon or other elements. Several allotropes of boron exist: amorphous boron is a brown powder and crystalline boron is black, extremely hard (about 9.5 on Mohs' scale), and a poor conductor at room temperature. Elemental boron is used as a dopant in the semiconductor industry.
The major uses of boron compounds are in sodium perborate bleaches, and the borax component of fiberglass insulation. Boron compounds play specialized roles as high-strength lightweight structural and refractory materials. They are used in glasses and ceramics to give them resistance to thermal shock. Boron-containing reagents are used for the synthesis of organic compounds, and as an intermediate in the synthesis of pharmaceuticals that do not contain boron.
In biology, borates have low toxicity in mammals (similar to table salt), but much more so to many arthropods. A boron-containing natural antibiotic is known. Small amounts of boron compounds play a strengthening role in the cell walls of all plants, making boron a necessary element in soils. Experiments indicate a role for boron as an ultratrace element in animals, but the nature of its role in animal physiology is unknown.
History and etymology
The name boron originates from the Arabic word بورق buraq or the Persian word بوره burah;[7] which are names for the mineral borax.[8]

Boron compounds were known thousands of years ago. Borax was known from the deserts of western Tibet, where it received the name of tincal, derived from the Sanskrit. Borax glazes were used in China from AD300, and some tincal even reached the West, where the Arabic alchemist Jābir ibn Hayyān seems to mention it in 700. Marco Polo brought some glazes back to Italy in the 13th century. Agricola, around 1600, reports the use of borax as a flux in metallurgy. In 1777, boric acid was recognized in the hot springs (soffioni) near Florence, Italy, and became known as sal sedativum, with mainly medical uses. The rare mineral is called sassolite, which is found at Sasso, Italy. Sasso was the main source of European borax from 1827 to 1872, at which date American sources replaced it.[9][10]
Boron was not recognized as an element until it was isolated by Sir Humphry Davy[11] and by Joseph Louis Gay-Lussac and Louis Jacques Thénard[12] in 1808 through the reaction of boric acid and potassium. Davy called the element boracium.[13] Jöns Jakob Berzelius identified boron as an element in 1824. The first pure boron was arguably produced by the American chemist W. Weintraub in 1909.[14][15]
Market trend
Estimated global consumption of boron rose to a record 1.8 million tonnes of B2O3 in 2005, following a period of strong growth in demand from Asia, Europe and North America. Boron mining and refining capacities are considered to be adequate to meet expected levels of growth through the next decade.
The form in which boron is consumed has changed in recent years. The use of ores like colemanite has declined following concerns over arsenic content. Consumers have moved towards the use of refined borates and boric acid that have a lower pollutant content. The average cost of crystalline boron is $5/g.[53]
Increasing demand for boric acid has led a number of producers to invest in additional capacity. Eti Mine Company of Turkey opened a new boric acid plant with the production capacity of 100,000 tonnes per year at Emet in 2003. Rio Tinto Group increased the capacity of its boron plant from 260,000 tonnes per year in 2003 to 310,000 tonnes per year by May 2005, with plans to grow this to 366,000 tonnes per year in 2006. Chinese boron producers have been unable to meet rapidly growing demand for high quality borates. This has led to imports of sodium tetraborate (borax) growing by a hundredfold between 2000 and 2005 and boric acid imports increasing by 28% per year over the same period.[54][55]
The rise in global demand has been driven by high growth rates in fiberglass and borosilicate production. A rapid increase in the manufacture of reinforcement-grade fiberglass in Asia with a consequent increase in demand for borates has offset the development of boron-free reinforcement-grade fiberglass in Europe and the USA. The recent rises in energy prices may lead to greater use of insulation-grade fiberglass, with consequent growth in the boron consumption. Roskill Consulting Group forecasts that world demand for boron will grow by 3.4% per year to reach 21 million tonnes by 2010. The highest growth in demand is expected to be in Asia where demand could rise by an average 5.7% per year.[54][56]
Applications
Insulation
The main use of boron compounds is in the form of sodium tetraborate pentahydrate (Na2B4O7) for making insulating fiberglass and sodium perborate bleach.[57]
Detergents formulations and bleaching agents
Borax is used in laundry products, mainly as a precursor to bleaches. Specifically, sodium perborate serves as a source of active oxygen in many detergents, laundry detergents, cleaning products, and laundry bleaches. It is also present in some tooth bleaching formulas.[57]
Glass and ceramics
Nearly all boron ore extracted from the Earth is destined for refinement into boric acid and sodium tetraborate. In the United States, 70% of the boron is used for the production of glass and ceramics.[58] Borosilicate glass, which is typically 12–15% B2O3, 80% SiO2, and 2% Al2O3, has a low coefficient of thermal expansion giving it a good resistance to thermal shock. Duran and Pyrex are two major brand names for this glass.[59]
Boron filaments are high-strength, lightweight materials that are used chiefly for advanced aerospace structures as a component of composite materials, as well as limited production consumer and sporting goods such as golf clubs and fishing rods.[60][61] The fibers can be produced by chemical vapor deposition of boron on a tungsten filament.[43][62]
Boron fibers and sub-millimeter sized crystalline boron springs are produced by laser-assisted chemical vapor deposition. Translation of the focused laser beam allows to produce even complex helical structures. Such structures show good mechanical properties (elastic modulus 450 GPa, fracture strain 3.7 %, fracture stress 17 GPa) and can be applied as reinforcement of ceramics or in micromechanical systems.[63]
Shielding in nuclear reactors
Boron shielding is used as a control for nuclear reactors, taking advantage of its high cross-section for neutron capture.
Semiconductor industry
Boron is a useful dopant for such semiconductors as silicon, germanium, and silicon carbide. Having one fewer valence electron than the host atom, it donates a hole resulting in p-type conductivity. Traditional method of introducing boron into semiconductors is via its atomic diffusion at high temperatures. This process uses either solid (B2O3), liquid (BBr3), or gaseous boron sources (B2H6 or BF3). However, after 1970s, it was mostly replaced by ion implantation, which relies mostly on BF3 as a boron source. Boron trichloride gas is also an important chemical in semiconductor industry, however not for doping but rather for plasma etching of metals and their oxides. Triethylborane is also injected into vapor deposition reactors as a boron source. Examples are the plasma deposition of boron-containing hard carbon films, silicon nitride-boron nitride films, and for doping of diamond film with boron.

PRICE

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